So strange.
Could you describe in detail what happens when you click the link "play single player". If this doesnt work there should be error log displayed.
Edited:
What happened when you tried this?this didnt work nor did it work when i changed to "C:\Rome Total War\RomeTW.exe" -mod:eb like you siad Lord.
You should try Bovi validation tool. Refer to https://forums.totalwar.org/vb/showthread.php?t=93236
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