The AI in MTW is better, especially the battle AI. The gap between the games' strategic-level AI is narrower, but MTW still holds the overall edge (it handles the Risk-style map better than Medieval 2's 3D map).
Personally, I find MTW to be superior in both regards. This is admittedly a more subjective issue, however, and I'm sure that just as many (if not more) will say that M2TW is better. Either way, your mileage may vary.
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