Because if you're always available and willing to drop anything to be with a girl, and she knows it, you get put at the bottom of the list. If she thinks that she only has one chance to get you, because you act like a jerk who doesn't need them, then they will want to go out with you right then.
For the same reason as I don't smother one of my little brothers with love: he's the only one who always hugs me goodnight and tells me he loves me and everything (7 year old), but because he's so readily available and will do it anytime, it doesn't mean that much to me. Whereas the 5 year old brother almost never does any of the above, so its alot better.
Basically you have to not let them know that you give a damn about them until after you start dating, and then you can be a bit nicer.
I've found that at least in high school, almost the only time being just a nice guy will land you a girl is if you're the rebound and you listen to all their crap and make them feel good. But rebounds are always short and usually pretty meaningless, in-between periods for her and you'll end up getting hurt (and no, I won't make a thread about how I was Green's rebound til today)
EDIT:
I was told that I was previously in the OP? I'd like to know what it said exactly? I don't care if it's a personal attack or not Sec, I'm really curious though
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