I have played three Long Campaigns on Normal - two for the Emperor and one for the Shogunate. In all my campaigns so far I have seen clans change side up to the point where your fame is significant enough where you are given a choice to continue fighting for Emperor/Shogunate or go it alone. I cannot remember any clan changing sides after that point. So it depends. While I usually prefer a solid frontline(s), if you are approaching this mentioned milestone I would be surprised if this clan changes sides. If you do attack him, of course you need to make sure all his Alliances are broken before the attack. Another option is to cause a Revolt, though you will suffer a small penalty on your relations with him (but he won't be around for long anyway).
TS!
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