You would need to posit why they were undertaking such smuggling, my is was not more securely transported, who it was to be sold to and why a former KGB agent would be undertaking such a dangerous venture without backing from Russia.
In fact, if Litvineko WAS smuggling Polonium that means he was stealing it from the Russian state to sell to Terrorists, possibly Chechens given his political leanings, which would be a compelling reason for Putin to kill him.
It would be poetic to do it with Polonium, no?
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