They had zero clue about vitamins.
Wiki on scurvy led me to james lind as well as stuff on scurvy
Some parts of antiquity knew citrus fruit warded off scurvy -- Caesar spiked his water with lemon in season or vinegar when not for example. The knowledge was never widely used.
Since the late 16th century in Europe various persons noted that fresh vegetables etc. seemed to minimize scurvy.
First formal rec to use citrus was early 1600s by a british EIC surgeon.
Physician James Lind did the first ever clinical trial in 1747 with a number of side by side cure efforts with scurvy patients. Results said citrus works, lemon juice takes navy by storm shortly thereafter.
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