Last night our (US) Public TV aired a program call Secrets of The Samurai Sword, which sounds very similar to the program TosaInu referred to.
It was indeed fascinating, particularly the parts about the thousand-years-old method of smelting the steel, then fashioning the sword and tempering it. All of it done without a modern understanding of chemistry and physics; done rather through "feel", after centuries of trial and error.
The program riveted my attention for the entire hour, and I found myself wanting more - for example: I'd have liked to have seen who & how the iron ore was harvested (they referred to it having come from "beaches" but showed no footage).
And I was surprised to learn that the curve of the blade is a by-product of the tempering process - that it wasn't merely hammered out that way.
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